松辽盆地低熟页岩原位改质过程孔隙演化研究
Porosity evolution during in-situ conversion process of low-maturity shale in Songliao Basin
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摘要: 低熟页岩油气资源量大,具有巨大的开发前景和潜力,尤其是松辽盆地,资源量达3 236×108 t. 目前对于松辽盆地北部的低熟页岩原位加热过程中孔隙大小及形态演化规律研究尚不足. 本文以松辽盆地北部低熟页岩为研究对象,利用热模拟实验,结合CT扫描、高压压汞、低温氮气吸附、扫描电镜等实验,揭示该区升温过程中孔隙发育特征,并对其演化过程和机理进行研究. 结果表明:350~375℃有机质热解程度大,生成大量的气孔和有机孔隙; 400~500℃有机质热解趋于完全,发育大量粒间孔隙和微裂隙,孔隙度和平均孔径增大. 总孔体积与平均孔径变化趋势基本一致,表现为升-降-升的过程. 0℃和300℃孔隙形状以窄狭缝型孔为主, 350℃孔隙转化为宽狭缝型孔, 375℃孔隙以两端开口的圆柱型孔为主, 400~500℃阶段孔隙转化为宽狭缝型孔.Abstract: The low-maturity shale oil and gas resources exhibit vast reserves and tremendous development potential, particularly in Songliao Basin with resources up to 323 600 Mt. However, current research on pore size and morphology evolution during in-situ heating of low-maturity shale in northern Songliao Basin remains insufficient. Taking the low-maturity shale in northern Songliao Basin as object, this study employs thermal simulation experiment combined with CT scanning, high-pressure mercury injection, low-temperature nitrogen adsorption, and scanning electron microscopy (SEM) to investigate the pore development characteristics during heating process, and analyze the evolution process and mechanism. The results show that at 350-375℃, the organic matter undergoes significant pyrolysis, generating abundant gas pores and organic pores; at 400-500℃, pyrolysis approaches completion, developing extensive intergranular pores and microfractures, with increased porosity and average pore size. The total pore volume and average pore diameter display a synchronized increase-decrease-increase trend. The pore morphology is dominated by slit-shaped pores with narrow openings at 0℃ and 300℃, transformed to slit-shaped pores with wide openings at 350℃, primarily open-ended cylindrical pores at 375℃, and reverting to slit-shaped pores with wide openings at 400-500℃.
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